NICKEL DIALKYLDITHIOCARBAMATES

Nickel bis(methylethyldithiocarbamate) Ni(MeEtN-CS2)2

Nickel bis(diethyldithiocarbamate) Ni(Et2N-CS2)2

Nickel bis(methyl-n-butyldithiocarbamate) Ni(MenBuN-CS2)2

Nickel bis(methyl-n-hexyldithiocarbamate) Ni(MenHex-CS2)2

Nickel (II) dialkyldithiocarbamates Ni(RR’2N-CS2)2 (RR’=Et2, MeEt, MenBu, MenHex) for NiSx by MOCVD

Nickel (II) dialkyldithiocarbamates Ni(RR’2N-CS2)2 (RR’= MeEt, Et2, MenBu, MenHex) were synthesized and characterized.

Ni(RR’2N-CS2)2 were applied as singe source precursors for the growth of nicke l sulfide NiSx films on glass substrates by low-pressure MOCVD. The deposited layers consisted of NiS1.03 phase, or of a mixture of NiS1.03 and NiS. The films were characterised by powder XRD, SEM, TEM and EDX.[[i]]

[i] P. O'Brien, J.H. Park, J. Waters, Thin Solid Films, 2003, Vol.431–432, p.502–505, Proc. Symp. B, Thin Film Chalcogenide Photovoltaic Materials, E-MRS Spring Meeting, « A single source approach to deposition of nickel sulfide thin films by LP-MOCVD », www.sciencedirect.com/science/article/pii/S004060900300244X

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