ZINC ALKYLS -DIALKYLDITHIOCARBAMATES

Neopentylzinc diethyldithiocarbamate Zn(CH2tBu)(S2C-NEt2)

Tert-butylzinc diethyldithiocarbamate Zn(tBu)( S2C-NEt2)

Neopentylzinc and tert-butylzinc diethyldithiocarbamates ( [Zn(CH2tBu)(S2C-NEt2)] and [Zn(tBu)(Se2C-NEt2) ] ) have been synthesized and characterized.  Both compound have been tested as single-source precursors for deposition ZnS thin films by MOCVD. [[i] ]

[i] M. Azad Malik, Majid Motevalli, John R. Walsh, Paul O'Brien, Organometallics, 1992, 11 (9), pp 3136–3139, DOI: 10.1021/om00045a033 “Neopentyl- or tert-butylzinc complexes with diethylthio- or diethylselenocarbamates: precursors for zinc chalcogens”

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